The actress, who hosted the awards show in Santa Monica, California, mocked the actor live on stage.
Olivia, 37, blasted Mark during a segment with comedian and actress Niecy Nash, 47.
She began by making a toast to “all the good guys in Hollywood,” as she raised a glass of champagne.
Sarcastically she thanked: “That studio executive who had me meet him in the hotel conference room instead of his actual hotel room.”
Niecy also attempted to make her own speech to men who spoke up at Golden Globes but Olivia interrupted, saying: “Actually, they didn’t really say much there.”
Then Olivia turned her attention to Mark, 46, after he was reported to have earned more than one million pounds to reshoot scenes for All the Money in the World.
Teasingly, the X Men star said: “I want to say thank you to the producers for paying Niecy and I the same amount of money and Mark Wahlberg a million dollars.”
All the Money in the World was released last year, the cast includes Michelle Williams, Christopher Plummer, Romain Duris and Timothy Hutton.
Also during the awards show, Olivia wore a variety of dazzling ensembles.
The first was a halter-neck dress that featured an array of jewels which dangled from the neckline.
Wearing her hair in loose curls which she let drape across one shoulder she successfully pulled off the glamorous Hollywood look.
Olivia completed the ensemble with rosy red lipstick, lashings of mascara and dark eyeliner.
Later, she wore a floral jumpsuit which gaped at the top to reveal a hint of cleavage.
Her stylish outfit matched that of Niecy’s, who also opted for a striking patterned dress.
However, Olivia’s most risqué attire was an embellished mini dress which featured geometric lines across the entire garment.
She finished off the look with a pair of sparkling stilettos and a slick of red lipstick.